catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO2]manganese(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine monosolvate dihydrate]

catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO2]manganese(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine monosolvate dihydrate]

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In the title compound, {[Mn(C15H8O7)(C10H8N2)(H2O)3]·C10H8N2·2H2O}n, the bridging mode of the coordinating 4,4′-bipyridine ligands leads to the formation of polymeric zigzag chains parallel to [0-11].The chains are separated by 4,4′-bipyridine and water solvent molecules.Within a chain, the MnII tokidoki hello kitty blind box atom is six-coordinated by two N atoms of the bridging 4,4′-bipyridine ligands, three water O atoms and one carboxylate O atom of a single deprotonated 3-(4-carboxyphenoxy)phthalic acid ligand.

Both coordinating and solvent 4,4′-bipyridine molecules are situated on centres of inversion.An intricate network of O—H.O 2014 dodge ram 1500 fender flares and O—H.

N hydrogen bonds involving the carboxy group, the coordinating water molecules and the two types of solvent molecules leads to the formation of a three-dimensional network.